Search for: All records

Abstract Geometrically frustrated kagome lattices are raising as novel platforms to engineer correlated topological electron flat bands that are prominent to electronic instabilities. Here, we demonstrate a phonon softening at thek_z = πplane in ScV₆Sn₆. The low energy longitudinal phonon collapses at ~98 K andq = $$\frac{1}{3}\frac{1}{3}\frac{1}{2}$$ $\frac{1}{3}\frac{1}{3}\frac{1}{2}$due to the electron-phonon interaction, without the emergence of long-range charge order which sets in at a different propagation vectorq_CDW = $$\frac{1}{3}\frac{1}{3}\frac{1}{3}$$ $\frac{1}{3}\frac{1}{3}\frac{1}{3}$. Theoretical calculations corroborate the experimental finding to indicate that the leading instability is located at$$\frac{1}{3}\frac{1}{3}\frac{1}{2}$$ $\frac{1}{3}\frac{1}{3}\frac{1}{2}$of a rather flat mode. We relate the phonon renormalization to the orbital-resolved susceptibility of the trigonal Sn atoms and explain the approximately flat phonon dispersion. Our data report the first example of the collapse of a kagome bosonic mode and promote the 166 compounds of kagomes as primary candidates to explore correlated flat phonon-topological flat electron physics. 

Low dimensional magnetism has been powerfully boosted as a promising candidate for numerous applications. The stability of the long-range magnetic order is directly dependent on the electronic structure and the relative strength of the competing magnetic exchange constants. Here, we report a comparative pressure-dependent theoretical and experimental study of the electronic structure and exchange interactions of two-dimensional ferromagnets CrBr 3 and Cr 2 Ge 2 Te 6 . While CrBr 3 is found to be a Mott–Hubbard-like insulator, Cr 2 Ge 2 Te 6 shows a charge-transfer character due to the broader character of the Te 5p bands at the Fermi level. This different electronic behaviour is responsible for the robust insulating state of CrBr 3 , in which the magnetic exchange constants evolve monotonically with pressure, and the proximity to a metal–insulator transition predicted for Cr 2 Ge 2 Te 6 , which causes a non-monotonic evolution of its magnetic ordering temperature. We provide a microscopic understanding for the pressure evolution of the magnetic properties of the two systems.